In-Line pH Probe / ORP (Redox) Probe

METTLER TOLEDO pH analyzer and ORP analyzer systems are quality process pH analyzers for measuring in-line pH or in-line ORP (redox). Our portfolio offers a variety of different pH and redox probes and analyzers for a range of applications:

• Hygienically designed pH analyzers for food and pharmaceutical
• pH and ORP analyzers for pure and ultrapure water
• ATEX and FM approved industrial pH analyzers
• Digital pH and ORP analyzers with predictive diagnostics
• Non-glass  probes for industrial pH analyzers

METTLER TOLEDO has manufactured in-line pH sensors since 1948, and we have been developing our expertise ever since. Some key questions regarding in-line pH analyzer selection include:

What is a pH analyzer?

A pH analyzer is a system used for in-line pH measurement, typically in an industrial process. A pH analyzer generally consists of three components: a pH sensor, a transmitter, and a process adaption or housing unit. Together these three parts make up a process pH analyzer used for control of pH in an industrial environment.  METTLER TOLEDO provides a wide range of different pH sensors to meet your in-line pH control needs.  Additionally, many of our pH sensors also offer a redox measurement; so that integrating a pH analyzer also lets you integrate an ORP analyzer.

What is pH?

pH (potential of hydrogen) is a figure used to express the acidity or alkalinity of a solution on a logarithmic scale. On this scale 7 is neutral; lower values are more acidic and higher values are more alkaline, with a maximum measurement of 14. In process applications, pH is generally measured with an in-line pH analyzer, thisis most commonly integrated using a  glass combination electrode for industrial pH measurement. Additionally, an inline pH probe generally requires a process adaption, cable and transmitter to complete the pH analyzer.

How does an in-line pH sensor work?

A typical process pH  sensoris made up of two separate electrodes built into one, a pH sensing electrode, and a reference electrode. In the simplest terms, a pH sensing electrode uses a special pH sensing glass membrane. H⁺ ions permeate the membrane creating a charge. The potential between the two electrodes is the measurement of hydrogen ions in the solution, giving the measure of pH. For more details, download the free pH Theory Guide.

What is the difference between a pH probe, a pH sensor and a pH electrode?

Absolutely nothing! The three terms are used interchangeably in the industry. They can be used for pH probes that are used on industrial pH analyzers or in laboratory measurement. You may also hear the term "pH meter". This can be used for a piece of laboratory equipment, or the term pH meter can also be used interchangeably with in-line pH analyzer.

How do I select the right pH probe for my pH analyzer?

For optimal pH measurement it is crucial to choose the right pH probe for each pH analyzer. The most important criteria are: chemical composition, homogeneity, temperature, process pressure, pH range and container size (length and width restrictions). The choice of pH sensor becomes of particular importance for non-aqueous, low conductivity, protein-rich and viscous samples where general-purpose glass electrodes are subject to various sources of error. The response time and accuracy of an in-line pH analyzer is dependent on a number of factors. Measurements at extreme pH values and temperatures, or low conductivity may take longer than those of aqueous solutions at room temperature with a neutral pH value.

How long does a pH probe last?

An inline pH probe lasts for varying amounts of time, depending on the conditions surrounding your in-line pH analyzer. A variety of factors play a role in the life of your pH sensor, including the quality of the pH probe, the media that it is in, the temperature it measures in and how well it is maintained. A well maintained pH probe generally lasts 6 months to 1 year in a routine, moderately clean application. While there are significant variances in the lifetime of pH probes, intelligent, digital sensors with ISM technology use an algorithm to determine the remaining lifetime on your pH sensor. pH analyzers with ISM technology predict sensor malfunction before it happens and can therefore dramatically reduce downtime.

How do I maintain the sensor on my in-line pH analyzer?

Most pH sensors operate maintenance free, but there are some clear examples of where maintenance is required. For example, in certain applications (such as sugar production) where an industrial pH analyzer has its sensor in a viscous solution, clogged diaphragms on the pH sensor need to be cleaned. Certain solutions (such as those used in varnish production) can also coat the pH sensor's membrane glass, causing a reduction in permeability. Without cleaning in these situations, you will get incorrect readings and reductions in sensor lifetime.

Another specific example is in pH analyzers that use a pH probe with refillable-liquid electrolyte. These pH analyzersneed the electrolyte to be topped-up when the level becomes close to being lower than the level of the sample solution. This maintenance prevents a reflux of the sample into the probe. The complete reference electrolyte should also be regularly changed, approximately once a month. This ensures that the electrolyte is fresh and that no crystallization occurs due to evaporation from the open filling port during measurement. It is important not to get any bubbles on the inside of the probe, especially near the junction. If this happens, the measurements will be unstable. To get rid of any bubbles, gently shake the probe in a vertical motion as with a fever thermometer.

How do I clean a process pH probe?

To clean a process pH probe, rinse it with deionized water after each measurement but never wipe it with a tissue. The surface of the paper tissue can scratch and damage the pH-sensitive glass membrane, removing the gel-layer and creating an electrostatic charge on the electrode. This electrostatic charge causes the measured signal to become very unstable. Special cleaning procedures may be necessary after contamination with certain samples. Some process pH analyzers can be integrated with a cleaning automation system that simplifies the cleaning process. This is particularly valuable in industrial pH monitoring applications where access to the sensor is limited.

How often should I calibrate and maintain a pH probe?

Regular maintenance and calibration of your pH probe are critical. How and how often to calibrate and maintain the probe on your pH analyzer depends on both the probe and the usage. In general, the best way to know when your pH analyzer needs calibrated or maintained is to use an intelligent pH sensor and transmitter with ISM technology. These pH analyzers use an algorithm to monitor the sensor's health and provide a measurement of Time to Maintenance and  an Adaptive Calibration Timer.

How do I store a pH sensor?

pH sensors should always be stored in reference electrolyte. This allows immediate use of the pH sensor when needed, and ensures a short response time. When stored dry for long periods, many pH sensors must be reactivated by soaking for several hours before installation in an in-line pH analyzer in order to get the optimal measuring results. If these measures are not sufficient, the electrode may be made functional by treating it with a special reactivation solution followed by subsequent conditioning in the reference electrolyte. Do not store a pH sensor in distilled water, as this will cause the pH sensor to have a longer response time.

What is redox potential? What is ORP?

Redox is short for reduction-oxidation reaction. It is a chemical reaction that changes the oxidation states of atoms. ORP stands for oxidation-reduction potential. Redox potential and ORP are two ways of saying the same thing. It is a millivolt measurement of the tendency of a chemical substance to oxidize. While the pH value measures the concentration (more precisely, activity) of hydrogen-ions, the ORP value is determined by the electron activity.

How does an ORP analyzer work?

An ORP analyzer uses an in-line ORP probe or redox probe.  At METTLER TOLEDO, many digital pH sensors also provide an ORP output, so the sensor operate as part of both a pH analyzer and OPR analyzer.  The ORP sensor works by measuring the difference between electron activity related to a noble metal like platinum or gold and a reference system that provides a stable potential, like those used in a pH measurement.

What is the shelf life of a pH probe or an ORP probe?

Whether used in an in-line pH analyzer or an in-line ORP analyzer, if a pH sensor or ORP sensor is stored at normal room temperature with its original storage cap and solution in place on the end of the electrode, it can last well over a year with no degradation in performance. If the storage solution is allowed to dry or leaks out due to storage at high temperatures, freezing or other causes, the life of the probe may be reduced significantly.

What should I look for in a pH analyzer for pure water applications?

pH measurement in pure water requires a pH electrode that ensures a consistent, stable measurement. Sensors like METTLER TOLEDO's pHure pH sensor feature a special low-resistance pH glass membrane, shielded flow chamber and a continuous outflow of electrolyte. Features like these and others allow for the stable and accurate measurement of pH and ORP that is required in pure water applications at power plants and microelectronics facilities.