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Crystallization of polymers occurs between the glass transition (Tg) and the melting temperature (Tm). Within this temperature range, molecular movement allows crystalline domains to form, which can occur during heating (cold crystallization) or during cooling from the melt. The crystal properties depend on the heating and cooling rates applied.
Understanding polymer crystallization behavior is essential for improving production processes, optimizing material properties, developing new materials, and conducting failure analysis. Thermal analysis techniques are ideal for studying crystallization behavior, which is critical for optimizing material properties and processing conditions.
In the webinar, we show how differential scanning calorimetry (DSC) and Flash DSC in particular provide important insight into reorganization processes, which require an extremely wide range of heating and cooling rates. We also present analytical examples using thermomechanical analysis (TMA), dynamic mechanical analysis (DMA), and hot-stage microscopy (TOA).
Join our live webinar and expand your understanding of polymer crystallization behavior. Don’t miss the opportunity to ask our experts your questions!
The crystallization process is initiated by a certain degree of cooling and begins with nucleation followed by growth. Heterogeneous nucleation is more common in polymers and can be accelerated by adding nucleation agents. Crystallization processes can be measured via non-isothermal crystallization, cold crystallization, and isothermal crystallization.
Join our live webinar and go to our dedicated polymer crystallization page to find out more!

Dr. Teresa Dennenwaldt
Dr. Teresa Dennenwaldt obtained her PhD in chemistry in 2013 and completed a postdoc at the Ecole Polytechnique Fédérale de Lausanne, Switzerland in the field of electron microscopy and spectroscopy. In 2018, she joined METTLER TOLEDO as an application specialist for Thermal Analysis. In her current position, she expertly uses, teaches, and supports DSC, TGA, TMA, and DMA instruments at the METTLER TOLEDO head office in Switzerland.