The water content determination in organic compounds is based on the reaction described by R. W. Bunsen
I2 + SO2 + 2 H2O → 2 HI + H2SO4
Karl Fischer discovered that this reaction could be used for water determinations in a nonaqueous system containing an excess of sulfur dioxide with methanol as a solvent
Reaction:
CH3OH + SO2 + 3 RN + I2 + H2O →(RNH)•SO4CH3 + 2 (RNH)I
Karl Fischer titration method is increasingly in demand for Water determination of products ,worldwide. It is a reliable technique and is transparent and comparable.
This application is used to determine the water content in organic raw materials and solvents by volumetric Karl Fischer titration, including ketones and aldehydes.